Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones

	Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones
	Wang, Fen 1; Liu, Yuchen 1,2; Qi, Zisong 1; Dai, Wei 2; Li, Xingwei 1
刊名	tetrahedron letters
	2014-11-19
卷号	55 期号:47 页码:6399-6402
关键词	Rhodium catalysis 3-Methylcyclohexenones Phenol Robinson annulation
英文摘要	a simple catalytic, redox-neutral access to 3-methylcyclohexenones has been developed via rhodium catalysis in the presence of an amine additive and ag2co3. this process utilized simple aldehydes and acetone as substrates and tolerates a variety of functional groups. disubstituted phenols were isolated in moderate yields when cu(oac)(2) was employed as an oxidant. (c) 2014 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	c-h activation ; alpha,beta-unsaturated ketones ; aerobic dehydrogenation ; cyclohexanones ; aromatization ; arylation ; arenes
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000344825300003
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145689]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Zhejiang Normal Univ, Sch Chem & Biol Sci, Jinhua 321004, Peoples R China
推荐引用方式 GB/T 7714	Wang, Fen,Liu, Yuchen,Qi, Zisong,et al. Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones[J]. tetrahedron letters,2014,55(47):6399-6402.
APA	Wang, Fen,Liu, Yuchen,Qi, Zisong,Dai, Wei,&Li, Xingwei.(2014).Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones.tetrahedron letters,55(47),6399-6402.
MLA	Wang, Fen,et al."Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones".tetrahedron letters 55.47(2014):6399-6402.