Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions

	Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions
	Guo, Ran-Ning 1,2; Cai, Xian-Feng 1; Shi, Lei 1; Chen, Zhang-Pei 1; Zhou, Yong-Gui 1
刊名	chemistry-a european journal
	2014-07-01
卷号	20 期号:27 页码:8343-8346
关键词	fluorination heterocycles hydrogenation nitro compounds rearomatization
英文摘要	an efficient and transition-metal-free approach was developed to access a series of fluorinated heteroaromatics in moderate to excellent yields. this one-pot procedure features a triple-relay transformation of rapid dearomatization, fluorination, and rearomatization processes, which represents a conceptually novel strategy of combining partial hydrogenation and electrophilic fluorination.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	copper-mediated fluorination ; asymmetric transfer hydrogenation ; late-stage fluorination ; c-h bonds ; catalyzed fluorination ; medicinal chemistry ; hantzsch esters ; aryl fluorides ; f bond ; palladium
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000338019300018
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145647]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China
推荐引用方式 GB/T 7714	Guo, Ran-Ning,Cai, Xian-Feng,Shi, Lei,et al. Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions[J]. chemistry-a european journal,2014,20(27):8343-8346.
APA	Guo, Ran-Ning,Cai, Xian-Feng,Shi, Lei,Chen, Zhang-Pei,&Zhou, Yong-Gui.(2014).Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions.chemistry-a european journal,20(27),8343-8346.
MLA	Guo, Ran-Ning,et al."Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions".chemistry-a european journal 20.27(2014):8343-8346.