Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer

	Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer
	Xie, Yong 1,2; Wang, Ting-Ting 2; Yang, Rui-Xia 2; Huang, Nian-Yu 1; Zou, Kun 1; Deng, Wei-Qiao 2
刊名	chemsuschem
	2014-08-01
卷号	7 期号:8 页码:2110-2114
关键词	co(2) fixation cyclic carbonates heterogeneous catalysis turnover frequencies polymers
英文摘要	zinc-coordinated conjugated microporous polymers (zn-cmps), prepared by linking salen zinc and 1,3,5-triethynylbenzene, exhibit extraordinary activities (turnover frequencies of up to 11600 h(-1)), broad substrate scope, and group tolerance for the synthesis of functional organic carbonates by coupling epoxides with co2 at 120 degrees c and 3.0 mpa without the use of additional solvents. the catalytic activity of zn-cmp is comparable to those of homogeneous catalysts and superior to those of other heterogeneous catalysts. this catalyst could be reused more than ten times without a significant decrease in performance.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	cyclic carbonate synthesis ; porous organic polymers ; high-surface-area ; coupling reactions ; salen complexes ; mild conditions ; ionic liquids ; epoxides ; dioxide ; catalyst
收录类别	SCI
语种	英语
WOS记录号	WOS:000340519500007
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145526]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.China Three Gorges Univ, Hubei Key Lab Nat Prod Res, Coll Chem & Life Sci, Yichang 443002, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xie, Yong,Wang, Ting-Ting,Yang, Rui-Xia,et al. Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer[J]. chemsuschem,2014,7(8):2110-2114.
APA	Xie, Yong,Wang, Ting-Ting,Yang, Rui-Xia,Huang, Nian-Yu,Zou, Kun,&Deng, Wei-Qiao.(2014).Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer.chemsuschem,7(8),2110-2114.
MLA	Xie, Yong,et al."Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer".chemsuschem 7.8(2014):2110-2114.