Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst

	Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst
	Yang, Yanliang 1,2; Du, Zhongtian 1; Ma, Jiping 1; Lu, Fang 1; Zhang, Junjie 1,2; Xu, Jie 1
刊名	chemsuschem
	2014-05-01
卷号	7 期号:5 页码:1352-1356
关键词	catalysis fructose hydrogenation hydrophobic tetrahydro-2 5-furandimethanol
通讯作者	徐杰
英文摘要	the production of chemicals directly from sugars is an important step in biomass conversion. herein, tetrahydro-2,5-furandimethanol (thfdm), obtained from fructose, is formed by using a combination of acid and hydrophobic ru/sio2 in a water/cyclohexane biphasic system. two key factors enable the high selectivity towards thfdm: modifying the hydrogenation catalyst so that it has hydrophobic properties, and the continuous hydrogenation of generated 5-(hydroxymethyl)furfural in the cyclohexane phase. moreover, the selectivity towards thfdm is found to depend strongly on the acid catalyst used.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	ion-exchange-resin ; aerobic oxidation ; glycerol hydrogenolysis ; renewable resources ; silica aerogels ; cyclic ethers ; biomass ; 2,5-diformylfuran ; chemicals ; fuels
收录类别	SCI
语种	英语
WOS记录号	WOS:000336249400015
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/144424]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Yanliang,Du, Zhongtian,Ma, Jiping,et al. Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst[J]. chemsuschem,2014,7(5):1352-1356.
APA	Yang, Yanliang,Du, Zhongtian,Ma, Jiping,Lu, Fang,Zhang, Junjie,&Xu, Jie.(2014).Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst.chemsuschem,7(5),1352-1356.
MLA	Yang, Yanliang,et al."Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst".chemsuschem 7.5(2014):1352-1356.