Vertically aligned carbon-coated titanium dioxide nanorod arrays on carbon paper with low platinum for proton exchange membrane fuel cells | |
Jiang, Shangfeng1,2; Yi, Baolian1; Zhang, Changkun1,2; Liu, Sa1,2; Yu, Hongmei1; Shao, Zhigang1 | |
刊名 | journal of power sources |
2015-02-15 | |
卷号 | 276期号:1页码:80-88 |
关键词 | Proton exchange membrane fuel cells Carbon-coated titanium dioxide nanorod arrays Low platinum loading |
通讯作者 | 俞红梅 ; 邵志刚 |
英文摘要 | carbon-coated titanium dioxide (tio2-c) has received much attention as a catalyst support in proton exchange membrane fuel cells. in this study, tio2 nanorod arrays (nrs) are hydrothermally grown on carbon paper and converted into tio2-c nrs by heat treatment at 900 degrees c under methane atmosphere. then, platinum nanoparticles are sputtered onto the tio2 nrs by physical vapor deposition to produce pt -tio2-c. the as-prepared pt-tio2-c exhibits high stability during accelerated durability tests. as compared with the commercial gas diffusion electrode (gde, 34.4% decrease), a minor reduction in the electrochemically active surface area of the pt-tio2-c electrode after 1500 cycles (10.6% decrease) is observed. when the as-prepared electrode with ultra-low platinum content (pt loading: 28.67 mu g cm(-2)) is employed as the cathode of a single cell, the electrode generates power that is 4.84 x that of the commercial gde (pt loading: 400 mu g cm(-2)). an electrode that generates power of 11.9 kw g(pt)(-1) (as the cathode) is proposed. the fabricated pt-tio2-c electrode can be used in proton exchange membrane fuel cells. (c) 2014 elsevier b.v. all rights reserved. |
学科主题 | 物理化学 |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | electrochemistry ; energy & fuels |
研究领域[WOS] | electrochemistry ; energy & fuels |
关键词[WOS] | high-performance ; nanowire arrays ; ultra-low ; electrocatalysts ; supercapacitors ; electrodes ; catalysts ; supports ; metals ; co |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000348747200011 |
公开日期 | 2016-05-09 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143789] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Shangfeng,Yi, Baolian,Zhang, Changkun,et al. Vertically aligned carbon-coated titanium dioxide nanorod arrays on carbon paper with low platinum for proton exchange membrane fuel cells[J]. journal of power sources,2015,276(1):80-88. |
APA | Jiang, Shangfeng,Yi, Baolian,Zhang, Changkun,Liu, Sa,Yu, Hongmei,&Shao, Zhigang.(2015).Vertically aligned carbon-coated titanium dioxide nanorod arrays on carbon paper with low platinum for proton exchange membrane fuel cells.journal of power sources,276(1),80-88. |
MLA | Jiang, Shangfeng,et al."Vertically aligned carbon-coated titanium dioxide nanorod arrays on carbon paper with low platinum for proton exchange membrane fuel cells".journal of power sources 276.1(2015):80-88. |
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