Mass-analyzed threshold ionization spectroscopy of trans-1-methoxynaphthalene cation and the methoxyl substitution effect | |
Shivatare, Vidya1,2; Zheng, Qiusha3,4; Zhang, Bing3,4; Ganguly, Tapan5; Tzeng, Wen Bih1 | |
刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
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2013-02-01 | |
卷号 | 284页码:16-20 |
关键词 | Resonant two-photon ionization Threshold ionization Cation spectroscopy trans-1-Methoxynaphthalene |
英文摘要 | We applied the two-color resonant two-photon mass-analyzed threshold ionization technique to record the cation spectra of trans-1-methoxynaphthalene via five intermediate levels. The adiabatic ionization energy of this molecule is determined to be 61357 +/- 5 cm(-1), which is smaller than that of naphthalene by 4330 cm(-1). This indicates that the interaction between the OCH3 substituent and the aromatic ring is stronger in the cationic D-0 state than that in the neutral S-0 state. Comparing these data of trans-1-methoxynaphthalene with those of naphthalene, we find that the frequency difference of each mode depends on the vibrational pattern and the OCH3 group involved in the overall molecular motion. (C) 2013 Elsevier Inc. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Physics, Atomic, Molecular & Chemical ; Spectroscopy |
研究领域[WOS] | Physics ; Spectroscopy |
关键词[WOS] | HIGH-RESOLUTION ; PHOTOELECTRON-SPECTROSCOPY ; ENERGY ; SPECTRA ; ZEKE ; NAPHTHALENE ; EXCITATION ; COMPLEX |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000317155500003 |
公开日期 | 2016-05-09 |
内容类型 | 期刊论文 |
源URL | [http://ir.wipm.ac.cn/handle/112942/843] ![]() |
专题 | 武汉物理与数学研究所_原子分子光物理研究部 |
作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Acad Sinica, Taiwan Int Grad Program, Taipei 115, Taiwan 3.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 5.Jadavpur Univ, Sch Laser Sci & Engn, Kolkata 700032, India |
推荐引用方式 GB/T 7714 | Shivatare, Vidya,Zheng, Qiusha,Zhang, Bing,et al. Mass-analyzed threshold ionization spectroscopy of trans-1-methoxynaphthalene cation and the methoxyl substitution effect[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2013,284:16-20. |
APA | Shivatare, Vidya,Zheng, Qiusha,Zhang, Bing,Ganguly, Tapan,&Tzeng, Wen Bih.(2013).Mass-analyzed threshold ionization spectroscopy of trans-1-methoxynaphthalene cation and the methoxyl substitution effect.JOURNAL OF MOLECULAR SPECTROSCOPY,284,16-20. |
MLA | Shivatare, Vidya,et al."Mass-analyzed threshold ionization spectroscopy of trans-1-methoxynaphthalene cation and the methoxyl substitution effect".JOURNAL OF MOLECULAR SPECTROSCOPY 284(2013):16-20. |
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