Direct Electrochemistry of Glucose Oxidase on Novel Free-Standing Nitrogen-Doped Carbon Nanospheres@Carbon Nanofibers Composite Film
Zhang,Xuping; Liu,Dong; Li,Libo; You,Tianyan
刊名scientific reports
2015
卷号5页码:9885
关键词DIRECT ELECTRON-TRANSFER FLAVIN ADENINE-DINUCLEOTIDE NANOTUBE ELECTRODES OXYGEN REDUCTION FACILE SYNTHESIS BIOSENSOR BORON ELECTROCATALYSTS PERFORMANCE GRAPHENE
通讯作者you,ty
英文摘要we have proposed a novel free-standing nitrogen-doped carbon nanospheres@carbon nanofibers (ncnss@cnfs) composite film with high processability for the investigation of the direct electron transfer (det) of glucose oxidase (gox) and the det-based glucose biosensing. the composites were simply prepared by controlled thermal treatment of electrospun polypyrrole nanospheres doped polyacrylonitrile nanofibers (ppynss@pan nfs). without any pretreatment, the as-prepared material can directly serve as a platform for gox immobilization. the cyclic voltammetry of immobilized gox showed a pair of well-defined redox peaks in o-2-free solution, indicating the det of gox. with the addition of glucose, the anodic peak current increased, while the cathodic peak current decreased, which demonstrated the det-based bioelectrocatalysis. the detection of glucose based on the det of gox was achieved, which displayed high sensitivity, stability and selectivity, with a low detection limit of 2 mu m and wide linear range of 12-1000 mu m. these results demonstrate that the as-obtained ncnss@cnfs can serve as an ideal platform for the construction of the thirdgeneration glucose biosensor.
收录类别SCI
语种英语
公开日期2016-05-09
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/64848]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhang,Xuping,Liu,Dong,Li,Libo,et al. Direct Electrochemistry of Glucose Oxidase on Novel Free-Standing Nitrogen-Doped Carbon Nanospheres@Carbon Nanofibers Composite Film[J]. scientific reports,2015,5:9885.
APA Zhang,Xuping,Liu,Dong,Li,Libo,&You,Tianyan.(2015).Direct Electrochemistry of Glucose Oxidase on Novel Free-Standing Nitrogen-Doped Carbon Nanospheres@Carbon Nanofibers Composite Film.scientific reports,5,9885.
MLA Zhang,Xuping,et al."Direct Electrochemistry of Glucose Oxidase on Novel Free-Standing Nitrogen-Doped Carbon Nanospheres@Carbon Nanofibers Composite Film".scientific reports 5(2015):9885.
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