Encapsulation of Ln(III) Ions/Dyes within a Microporous Anionic MOF by Post-synthetic Ionic Exchange Serving as a Ln(III) Ion Probe and Two-Color Luminescent Sensors
Zhao,Shu-Na; Song,Xue-Zhi; Zhu,Min; Meng,Xing; Wu,Lan-Lan; Feng,Jing; Song,Shu-Yan; Zhang,Hong-Jie
刊名chemistry-a european journal
2015
卷号21期号:27页码:9748-9752
关键词METAL-ORGANIC FRAMEWORKS POROUS COORDINATION POLYMER CATION-EXCHANGE TUNABLE LUMINESCENCE ADSORPTION MOLECULES DYE EMISSION GAS ENHANCEMENT
通讯作者song,sy
英文摘要a new anionic framework {[me2nh2](0.125)[in-0.125(h2l)(0.25)]center dot xdmf}(n) (1) with one-dimensional (1d) channels along the c axis of about 13.06 x 13.06 angstrom(2), was solvothermally synthesized and well characterized. post-synthetic cation exchange of 1 with eu3+, tb3+, dy3+, sm3+ afforded lanthanide(iii)-loaded materials, ln(3+) @1, with different luminescent behavior, indicating that compound 1 could be used as a potential luminescent probe toward different lanthanide(iii) ions. additionally, compound 1 exhibits selective adsorption ability toward cationic dyes. moreover, the rhb@1 realized the probing of different organic solvent molecules by tuning the energy transfer efficiency between two different emissions, especially for sensing dmf. this work highlights the practical application of luminescent guest@-mofs as sensors, and it paves the way toward other one/multi-color luminescent host-guest systems by rational selection of mof hosts and guest chromophores with suitable emissive colors and energy levels.
收录类别SCI
语种英语
WOS记录号WOS:000357027300024
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/64826]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhao,Shu-Na,Song,Xue-Zhi,Zhu,Min,et al. Encapsulation of Ln(III) Ions/Dyes within a Microporous Anionic MOF by Post-synthetic Ionic Exchange Serving as a Ln(III) Ion Probe and Two-Color Luminescent Sensors[J]. chemistry-a european journal,2015,21(27):9748-9752.
APA Zhao,Shu-Na.,Song,Xue-Zhi.,Zhu,Min.,Meng,Xing.,Wu,Lan-Lan.,...&Zhang,Hong-Jie.(2015).Encapsulation of Ln(III) Ions/Dyes within a Microporous Anionic MOF by Post-synthetic Ionic Exchange Serving as a Ln(III) Ion Probe and Two-Color Luminescent Sensors.chemistry-a european journal,21(27),9748-9752.
MLA Zhao,Shu-Na,et al."Encapsulation of Ln(III) Ions/Dyes within a Microporous Anionic MOF by Post-synthetic Ionic Exchange Serving as a Ln(III) Ion Probe and Two-Color Luminescent Sensors".chemistry-a european journal 21.27(2015):9748-9752.
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