Photoelectrochemical water splitting in an organic artificial leaf

	Photoelectrochemical water splitting in an organic artificial leaf
	Esiner, Serkan 1; Willems, Robin E. M.1; Furlan, Alice 1; Li, Weiwei 1,2; Wienk, Martijn M.1,3; Janssen, Rene. A. J.1,3
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2015
卷号	3 期号:47 页码:23936-23945
英文摘要	Photoelectrochemical water splitting is demonstrated in an organic artificial leaf composed of a triple junction polymer solar cell for light absorption and charge generation and low-overpotential catalytic electrodes for hydrogen and oxygen evolution. For small area solar cells (<0.1 cm(2)), a solar to hydrogen conversion efficiency of 5.4% is obtained using RuO2 catalysts. Using earth-abundant NiMoZn and Co3O4 catalysts for hydrogen and oxygen evolution, the efficiency is 4.9%. For larger area (1.7 cm(2)) solar cell devices the solar to hydrogen efficiency with RuO2 catalysts reduces to 3.6% as a consequence of an increased overpotential for water splitting. This shifts the operating point of the water splitting device beyond the maximum power point of the solar cell and reduces the photocurrent.
收录类别	SCI
语种	英语
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/29285]
专题	化学研究所_有机固体实验室
作者单位	1.Eindhoven Univ Technol, Mol Mat & Nanosyst & Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands 2.Chinese Acad Sci, Organ Solids Lab, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Dutch Inst Fundamental Energy Res, NL-5612 AJ Eindhoven, Netherlands
推荐引用方式 GB/T 7714	Esiner, Serkan,Willems, Robin E. M.,Furlan, Alice,et al. Photoelectrochemical water splitting in an organic artificial leaf[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(47):23936-23945.
APA	Esiner, Serkan,Willems, Robin E. M.,Furlan, Alice,Li, Weiwei,Wienk, Martijn M.,&Janssen, Rene. A. J..(2015).Photoelectrochemical water splitting in an organic artificial leaf.JOURNAL OF MATERIALS CHEMISTRY A,3(47),23936-23945.
MLA	Esiner, Serkan,et al."Photoelectrochemical water splitting in an organic artificial leaf".JOURNAL OF MATERIALS CHEMISTRY A 3.47(2015):23936-23945.