Synthesis of polymer protected AuNPs for silver ions detection | |
Xu, Xiaozhe1,2; Qiao, Juan2; Qi, Li2; Wang, Luliang2,3,4; Zhang, Shufeng1 | |
刊名 | SCIENCE CHINA-CHEMISTRY
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2015-06-01 | |
卷号 | 58期号:6页码:1065-1072 |
关键词 | silver ion gold nanoparticle polymer |
英文摘要 | Herein, a novel probe based on poly(N,N'-methylenebisacylamide) protected AuNPs (PDMAM-AuNPs) was developed for determination of silver ions. The thiol-terminated PDMAM was synthesized by the reversible addition fragmentation chain transfer radical polymerization. Then, the PDMAM-AuNPs were prepared by a simple, one-pot and green process. It has been observed that existence of the silver ions evoked a small red-shift to the emission peak of PDMAM-AuNPs and an obvious increase in UV absorption. The detection limit of the present method for silver ions was 0.5 mu mol/L, with a linear range of 1.0-1000 mu mol/L. Moreover, the possible mechanism for enhanced UV absorption intensity with enlarged diameter of PDMAM-AuNPs was explored and discussed briefly. The results demonstrated that silver ions could be detected by the PDMAM-AuNPs based colorimetric assays, further opening up new ways for the visualization and quantification of silver ions involved in our daily life. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-09 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/28144] ![]() |
专题 | 化学研究所_活体分析化学实验室 |
作者单位 | 1.Tianjin Normal Univ, Coll Chem, Tianjin 300387, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Inst Chem, Beijing 100190, Peoples R China 3.Shantou Univ, Dept Chem, Shantou 515063, Peoples R China 4.Shantou Univ, Res Inst Biomed & Adv Mat, Shantou 515063, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Xiaozhe,Qiao, Juan,Qi, Li,et al. Synthesis of polymer protected AuNPs for silver ions detection[J]. SCIENCE CHINA-CHEMISTRY,2015,58(6):1065-1072. |
APA | Xu, Xiaozhe,Qiao, Juan,Qi, Li,Wang, Luliang,&Zhang, Shufeng.(2015).Synthesis of polymer protected AuNPs for silver ions detection.SCIENCE CHINA-CHEMISTRY,58(6),1065-1072. |
MLA | Xu, Xiaozhe,et al."Synthesis of polymer protected AuNPs for silver ions detection".SCIENCE CHINA-CHEMISTRY 58.6(2015):1065-1072. |
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