Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions

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	Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions
	Guo, Ya-Fei; Xu, Bao-Hua; Li, Ting; Wang, Lei; Zhang, Suo-Jiang
刊名	ORGANIC CHEMISTRY FRONTIERS
	2016
卷号	3 期号:1 页码:47-52
ISSN号	2052-4129
英文摘要	The efficient cobalt(II) catalyzed oxidative alkoxylation of aldehydes, a method directly leading to the corresponding esters, is presented. Mechanism studies provide extensive insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion. The in situ generated hypoiodites (IO-/IO2-) mainly from conversion of I-3(-) to IO3- account for a cooperative effect with the oxygen centered radical species to make the important hydrogen abstraction of hemiacetal intermediates more selective, thereby offering high efficiency.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	CATALYZED DIRECT ARYLATION ; CROSS-COUPLING REACTIONS ; C-H BOND ; TRANSITION-METALS ; AEROBIC OXIDATION ; AROMATIC IMINES ; CARBON-HYDROGEN ; BENZYL ALCOHOLS ; AMIDATION ; AMINES
收录类别	SCI
语种	英语
WOS记录号	WOS:000366864700007
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/20196]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,et al. Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(1):47-52.
APA	Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,Wang, Lei,&Zhang, Suo-Jiang.(2016).Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions.ORGANIC CHEMISTRY FRONTIERS,3(1),47-52.
MLA	Guo, Ya-Fei,et al."Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions".ORGANIC CHEMISTRY FRONTIERS 3.1(2016):47-52.