2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates

CORC > 苏州纳米技术与纳米仿生研究所 > 中国科学院苏州纳米技术与纳米仿生研究所 > 学科交叉综合研究部 > 潘革波团队

	2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates
	Pan GB (潘革波)
刊名	Journal of the American Chemical Society
	2010-02-03
卷号	132 期号:4 页码:1328-1333
通讯作者	Pan GB (潘革波)
合作状况	其它
英文摘要	The synthesis and scanning tunneling microscopy (STM) investigations of shape-persistent arylene-ethynylene-butadiynylene macrocycles along with their codeposites with metallacycles are reported. 2D ordered arrays of macrocycles and macrocycle/metallacycle architectures (1:1) have been obtained on HOPG by self-assembly under ambient conditions. It is found that the ordered macrocycle array acts as a template for the deposition of the adlayer molecules. For each underlying macrocycle, one metallacycle has been detected. The unit-cell data of both, the macrocycles; and their codeposites, show that the structural information of the macrocycle layer is perfectly transformed to the guest molecules. A rather unexpected observation is that the present compound could not be coadsorbed with C(60), indicating that only a minor change in the structure of the macrocycle has a dramatic effect on the ability of the monolayer to bind additional guest molecules.
收录类别	SCI ; EI
语种	英语
WOS记录号	WOS:000275084800048
公开日期	2011-03-14
内容类型	期刊论文
源URL	[http://58.210.77.100/handle/332007/366]
专题	苏州纳米技术与纳米仿生研究所_学科交叉综合研究部_潘革波团队
通讯作者	Pan GB (潘革波)
推荐引用方式 GB/T 7714	Pan GB . 2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates[J]. Journal of the American Chemical Society,2010,132(4):1328-1333.
APA	Pan GB .(2010).2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates.Journal of the American Chemical Society,132(4),1328-1333.
MLA	Pan GB ."2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates".Journal of the American Chemical Society 132.4(2010):1328-1333.