CoPt/CeO2 catalysts for the growth of narrow diameter semiconducting single-walled carbon nanotubes | |
Tang, L(唐磊); Li, TT(李涛涛); Li, CW(李朝威); Ling, L(凌琳); Zhang, K(张凯); Yao, YG(姚亚刚) | |
刊名 | NANOSCALE |
2015 | |
卷号 | 7期号:46页码:6 |
通讯作者 | Yao, YG (姚亚刚) |
英文摘要 | For the application of single-walled carbon nanotubes (SWNTs) in nanoelectronic devices, effective techniques for the growth of semiconducting SWNTs (s-SWNTs) with a specific diameter are still a great challenge. Herein, we report a facile strategy for the selective growth of narrow diameter distributed s-SWNTs using CoPt/CeO2 catalysts. The addition of Pt into a Co catalyst dramatically reduces the diameter distributions and even the chirality distributions of the as-grown SWNTs. Oxygen vacancies that are provided by mesoporous CeO2 are responsible for creating an oxidative environment to in situ etch metallic SWNTs (m-SWNTs). Atomic force microscope (AFM) and Raman spectroscopy characterizations indicate a narrow diameter distribution of 1.32 +/- 0.03 nm and the selective growth of s-SWNTs to 93%, respectively. In addition, electronic transport measurements also confirm that the I-on/I-off ratio is mainly in the order of similar to 10(3). This work provides an effective strategy for the facile fabrication of narrow diameter distributed s-SWNTs, which will be beneficial to fundamental research and the broad application of SWNTs for future nanoelectronics. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-03 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinano.ac.cn/handle/332007/3451] |
专题 | 苏州纳米技术与纳米仿生研究所_先进材料研究部_姚亚刚团队 |
推荐引用方式 GB/T 7714 | Tang, L,Li, TT,Li, CW,et al. CoPt/CeO2 catalysts for the growth of narrow diameter semiconducting single-walled carbon nanotubes[J]. NANOSCALE,2015,7(46):6. |
APA | Tang, L,Li, TT,Li, CW,Ling, L,Zhang, K,&Yao, YG.(2015).CoPt/CeO2 catalysts for the growth of narrow diameter semiconducting single-walled carbon nanotubes.NANOSCALE,7(46),6. |
MLA | Tang, L,et al."CoPt/CeO2 catalysts for the growth of narrow diameter semiconducting single-walled carbon nanotubes".NANOSCALE 7.46(2015):6. |
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