Controllable Low-Temperature Chemical Vapor Deposition Growth and Morphology Dependent Field Emission Property of SnO2 Nanocone Arrays with Different Morphologies
Li, XB ; Wang, XW(王学文) ; Shen, Q ; Zheng, J ; Liu, WH ; Zhao, H ; Yang, F ; Yang, HQ
刊名ACS APPLIED MATERIALS & INTERFACES
2013-04-24
卷号5期号:8页码:3033-3041
关键词SnO2 nanocone arrays VS growth field-emission
通讯作者Yang, HQ
英文摘要Vertically aligned SnO2 nanocones with different morphologies have been directly grown on fluorine-doped tin oxide (FTO) glass substrates in a large area by heating a mixture of stannous chloride dihydrate (SnCl2·2H2O) and anhydrous zinc chloride (ZnCl2) at 600 °C in air. Control over the SnO2 nanocone arrays with different morphologies is achieved by adjusting the heat treatment time. The SnO2 nanocones are single crystalline with the tetragonal structure. A single-layer SnO2 nanoparticle film is first formed via the vapor–solid (VS) process due to the decentralization function of ZnCl2 vapor, and the SnO2 nanoparticles served as seeds and grew into nanocone arrays via the VS process. The sharp-tipped nanostructure formation may originate from a concentration gradient of reactant in the growth process. The as-obtained whiskerlike nanocone arrays exhibit enhanced field emission properties in comparison with typical nanoconelike structure arrays and other SnO2 nanostructured materials reported previously, and the turn-on field and field-enhancement factor is 1.19 V/μm and 3110, respectively. The experimental result is consistent with the Utsumi’s relative figure of merit for pillar-shaped emitters.
收录类别SCI ; EI
语种英语
WOS记录号WOS:000318205000029
公开日期2014-01-10
内容类型期刊论文
源URL[http://ir.sinano.ac.cn/handle/332007/1274]  
专题苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_张珽团队
推荐引用方式
GB/T 7714
Li, XB,Wang, XW,Shen, Q,et al. Controllable Low-Temperature Chemical Vapor Deposition Growth and Morphology Dependent Field Emission Property of SnO2 Nanocone Arrays with Different Morphologies[J]. ACS APPLIED MATERIALS & INTERFACES,2013,5(8):3033-3041.
APA Li, XB.,Wang, XW.,Shen, Q.,Zheng, J.,Liu, WH.,...&Yang, HQ.(2013).Controllable Low-Temperature Chemical Vapor Deposition Growth and Morphology Dependent Field Emission Property of SnO2 Nanocone Arrays with Different Morphologies.ACS APPLIED MATERIALS & INTERFACES,5(8),3033-3041.
MLA Li, XB,et al."Controllable Low-Temperature Chemical Vapor Deposition Growth and Morphology Dependent Field Emission Property of SnO2 Nanocone Arrays with Different Morphologies".ACS APPLIED MATERIALS & INTERFACES 5.8(2013):3033-3041.
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