Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration | |
Zhu LZ(祝刘正); Wang CZ(王聪芝)![]() ![]() ![]() ![]() ![]() ![]() | |
刊名 | CRYSTENGCOMM
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2015 | |
卷号 | 17期号:15页码:3031-3040 |
通讯作者 | 石伟群 |
英文摘要 | Two novel uranyl coordination polymers, namely, UO2(bptc)(H(2)bpy)center dot(bpy) (1) and (UO2)(3)(bptc)(1.5)(phen)(2)(H2O)(2)center dot H2O (2) (H(4)bptc = 3,3',4,4'-benzophenonetetracarboxylic acid; bpy = 4,4'-bipyridine; phen = 1,10-phenanthroline), have been obtained via a hydrothermal method based on a semi-rigid aromatic tetracarboxylic ligand and two different auxiliary or templating N-containing ligands. Complex 1 shows a one-dimensional (1D) structure derived from double chains with two types of rings arranged alternately, which further exhibits an intriguing 3D supramolecular network induced by diverse non-covalent interactions. Complex 2 displays a dislocated "double floor" of a 2D structure (2D zigzag layers), in which the carboxylate groups of the bptc(4)-ligand adopt a variety of fascinating bridging modes. In addition, quantum chemical calculations were used to investigate the coordination properties and bonding nature of the as-synthesized complexes, and the results indicate that in these two complexes the 5f, 6d, and 7p orbitals of uranium and 2p orbitals of O and N atoms mainly contribute to the covalency of the U-O and U-N bonds. |
学科主题 | Chemistry; Crystallography |
类目[WOS] | Chemistry, Multidisciplinary ; Crystallography |
收录类别 | SCI |
WOS记录号 | WOS:000352142800015 |
公开日期 | 2016-05-03 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/228360] ![]() |
专题 | 高能物理研究所_院士 高能物理研究所_多学科研究中心 |
推荐引用方式 GB/T 7714 | Zhu LZ,Wang CZ,Mei L,et al. Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration[J]. CRYSTENGCOMM,2015,17(15):3031-3040. |
APA | 祝刘正.,王聪芝.,梅雷.,王琳.,赵宇亮.,...&Shi, WQ.(2015).Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration.CRYSTENGCOMM,17(15),3031-3040. |
MLA | 祝刘正,et al."Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration".CRYSTENGCOMM 17.15(2015):3031-3040. |
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