Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 固体废弃物处理与资源化实验室

	Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor
	Gai, Chao; Dong, Yuping; Lv, Zhaochuan; Zhang, Zhaoling; Liang, Jingcui; Liu, Yantao
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2015-07-06
卷号	40 期号:25 页码:7956-7964
关键词	Tar Phenol Pyrolysis Kinetics Micro fluidized bed reactor
英文摘要	Thermal cracking characteristic of phenol as the model compound of biomass tar was investigated on a micro fluidized bed reactor. Pyrolysis kinetics for individual gaseous component, including hydrogen, methane, carbon monoxide and carbon dioxide were determined based on the iso-conversional and model-fitting approaches. Results indicated that carbon monoxide accounted for the biggest percentage of the total gas yield during pyrolysis of phenol. The evolution profiles of hydrogen energy and carbon monoxide were more affected by reaction temperature compared to methane and carbon dioxide. In the major conversion fraction from 20% to 80%, the apparent activation energies of methane (49.67 kJ/mol) and carbon dioxide (30.87 kJ/mol) were lower than that of hydrogen (145.2 kJ/mol) and carbon monoxide (53.35 kJ/mol). The most probable reaction mechanism for the formation of hydrogen and methane was three-dimension diffusion while chemical reaction and contracting sphere could describe the generation of carbon monoxide and carbon dioxide, respectively. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
研究领域[WOS]	Chemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS记录号	WOS:000356556700006
公开日期	2016-03-15
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/32497]
专题	生态环境研究中心_固体废弃物处理与资源化实验室
推荐引用方式 GB/T 7714	Gai, Chao,Dong, Yuping,Lv, Zhaochuan,et al. Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2015,40(25):7956-7964.
APA	Gai, Chao,Dong, Yuping,Lv, Zhaochuan,Zhang, Zhaoling,Liang, Jingcui,&Liu, Yantao.(2015).Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,40(25),7956-7964.
MLA	Gai, Chao,et al."Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 40.25(2015):7956-7964.