Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system
	Wang, K; Fei, ZJ; Wang, J; Wu, Z; Li, CH; Xie, LD
刊名	MATERIALS CHEMISTRY AND PHYSICS
	2015
卷号	163 页码:73—87
关键词	QUASI-CHEMICAL MODEL ELECTROMOTIVE-FORCE MEASUREMENTS SILVER-CHLORIDE AGCL-KCL POTASSIUM-CHLORIDE HALIDE MIXTURES SALT SYSTEMS OPTIMIZATION TRICHLORIDE PSEUDOPOTENTIALS
ISSN号	0254-0584
通讯作者	Wang, K (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China.
英文摘要	The present investigation is aimed at deriving a set of self-consistent thermodynamic functions for the AgCl-CoCl2-InCl3-KCl quaternary system within the framework of the CALPHAD approach. All the previous reported thermodynamic parameters for the binary subsystems were initially reviewed and adopted, and critical thermodynamic evaluations and optimizations were later performed on the unavailable AgCl-KCl and InCl3-KCl systems in terms of the required phase equilibria and thermochemical data from experimental measurements and theoretical predictions (First-principles method and empirical equation). The Modified Quasi-Chemical model were applied to describing the molten salt phase, while all the intermediate phases were treated as the stoichiometric compounds due to no observation of the homogeneity composition range. Various phase equilibria and thermodynamic properties in the ternary and quaternary systems could be facilely calculated based upon the ultimate thermodynamic database established in this case, which will support beneficial instructions in the related industrial processes. (C) 2015 Elsevier B.V. All rights reserved.
语种	英语
WOS记录号	WOS:000365361500009
公开日期	2016-03-08
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/25081]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Wang, K,Fei, ZJ,Wang, J,et al. Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system[J]. MATERIALS CHEMISTRY AND PHYSICS,2015,163:73—87.
APA	Wang, K,Fei, ZJ,Wang, J,Wu, Z,Li, CH,&Xie, LD.(2015).Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system.MATERIALS CHEMISTRY AND PHYSICS,163,73—87.
MLA	Wang, K,et al."Thermodynamic description of the AgCl-CoCl2-InCl3-KCl system".MATERIALS CHEMISTRY AND PHYSICS 163(2015):73—87.