High electrocatalytic activity for borohydride oxidation on palladium nanocubes enclosed by {200} facets

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	High electrocatalytic activity for borohydride oxidation on palladium nanocubes enclosed by {200} facets
	Qin, HY; Chen, KJ; Zhu, C; Liu, JB; Wang, J; He, Y; Chi, HZ; Ni, HL; Ji, ZG
刊名	JOURNAL OF POWER SOURCES
	2015
卷号	299 页码:241—245
关键词	OXYGEN REDUCTION REACTION FUEL-CELL CO OXIDATION SODIUM-BOROHYDRIDE ANODE CATALYSTS PD ELECTROOXIDATION PERFORMANCE NANOPARTICLES REACTIVITY
ISSN号	0378-7753
通讯作者	Liu, JB (reprint author), Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China.
英文摘要	Pd nanocubes enclosed by {200} facets are synthesized and used as an anode catalyst in direct borohydride fuel cell (DBFC) to study the electrocatalytic activity of Pd towards borohydride oxidation reaction (BOR) by modifying its surface atomic structure. A 7e reaction towards BOR is implemented on Pd nanocubes with a borohydride concentration as high as 3.26 M. The cell using Pd nanocubes as anode catalyst exhibits an obvious higher power density than the cell using commercial Pd/C, and maintained 99% of its voltage after 50 h stability test. It suggests that the Pd nanocubes could be a promising anode catalyst for the DBFC application. (C) 2015 Elsevier B.V. All rights reserved.
语种	英语
WOS记录号	WOS:000363907400029
公开日期	2016-03-08
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/24942]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Qin, HY,Chen, KJ,Zhu, C,et al. High electrocatalytic activity for borohydride oxidation on palladium nanocubes enclosed by {200} facets[J]. JOURNAL OF POWER SOURCES,2015,299:241—245.
APA	Qin, HY.,Chen, KJ.,Zhu, C.,Liu, JB.,Wang, J.,...&Ji, ZG.(2015).High electrocatalytic activity for borohydride oxidation on palladium nanocubes enclosed by {200} facets.JOURNAL OF POWER SOURCES,299,241—245.
MLA	Qin, HY,et al."High electrocatalytic activity for borohydride oxidation on palladium nanocubes enclosed by {200} facets".JOURNAL OF POWER SOURCES 299(2015):241—245.