Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites

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	Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites
	Meng, Qiyan 1,2; Xin, Hongchuan 2; Zhang, Yufei 2; Huang, Yan 1; Yi, Xianfeng 3; Sun, Yuanyuan 2; Zhong, Shifa 2; Li, Xuebing 2
刊名	SCIENCE OF ADVANCED MATERIALS
	2015-11-01
卷号	7 期号:11 页码:2343-2351
关键词	ZSM-5 Steam Treatment Ethanol Dehydration Ethylene Acidity
英文摘要	The steam-treated ZSM-5 zeolites are characterized by XRD, N-2 sorption, SEM, Al-27 MAS NMR and NH3-TPD techniques. The steaming procedures do not alter textural structures, but generate significant variations in the acidity. The catalytic properties of steam-treated ZSM-5 catalysts in dehydration of ethanol into ethylene are investigated in a fixed bed reactor at 150-350 degrees C and an atmospheric pressure. The decreased total acid sites and increased ratio of weak acid to strong acid after steam treatment may suppress ethylene from secondary reactions, and therefore lead to improved ethylene selectivity at higher temperature. Compared to parent ZSM-5, ZSM-5 treated at 600 degrees C (ZSM-600) shows excellent stability for ethylene production. The reaction conditions (space velocity and ethanol partial pressure) have significant influences on ethanol conversion and ethylene selectivity.
WOS标题词	Science & Technology ; Technology ; Physical Sciences
类目[WOS]	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
研究领域[WOS]	Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]	SOLID ACID CATALYSTS ; HZSM-5 ZEOLITE ; THEORETICAL CALCULATION ; AQUEOUS-ETHANOL ; STATE NMR ; P-31 NMR ; CONVERSION ; H-ZSM-5 ; DEALUMINATION ; METHANOL
收录类别	SCI
语种	英语
WOS记录号	WOS:000366295900010
公开日期	2016-03-01
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/9099]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Xinjiang Univ, Coll Chem & Chem Engn, Key Lab Oil & Gas Fine Chem, Minist Educ, Urumqi 830046, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式 GB/T 7714	Meng, Qiyan,Xin, Hongchuan,Zhang, Yufei,et al. Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites[J]. SCIENCE OF ADVANCED MATERIALS,2015,7(11):2343-2351.
APA	Meng, Qiyan.,Xin, Hongchuan.,Zhang, Yufei.,Huang, Yan.,Yi, Xianfeng.,...&Li, Xuebing.(2015).Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites.SCIENCE OF ADVANCED MATERIALS,7(11),2343-2351.
MLA	Meng, Qiyan,et al."Catalytic Dehydration of Ethanol to Ethylene Over Steam-Treated ZSM-5 Zeolites".SCIENCE OF ADVANCED MATERIALS 7.11(2015):2343-2351.