Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink
Zhang, Yu1,2,3; Zhu, Pengli1,4; Li, Gang1; Zhao, Tao1; Fu, Xianzhu1; Sun, Rong1; Zhou F(周峰)2; Wong, Ching-ping4,5
刊名ACS Applied Materials and Interfaces
2014
卷号6期号:1页码:560-567
关键词copper nanoparticles monodisperse antioxidative large scale flexible conductors
ISSN号1944-8244
通讯作者Zhu, Pengli ; Sun, Rong
英文摘要Monodisperse copper nanoparticles with high purity and antioxidation properties are synthesized quickly (only 5 min) on a large scale (multigram amounts) by a modified polyol process using slightly soluble Cu(OH)2 as the precursor, l-ascorbic acid as the reductant, and PEG-2000 as the protectant. The resulting copper nanoparticles have a size distribution of 135 ± 30 nm and do not suffer significant oxidation even after being stored for 30 days under ambient conditions. The copper nanoparticles can be well-dispersed in an oil-based ink, which can be silk-screen printed onto flexible substrates and then converted into conductive patterns after heat treatment. An optimal electrical resistivity of 15.8 μΩ cm is achieved, which is only 10 times larger than that of bulk copper. The synthesized copper nanoparticles could be considered as a cheap and effective material for printed electronics.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Basic Research Program of China (973 Program) (2012CB933700-G);the National Natural Science Foundation of China (21101165);the Guangdong Innovative Research Team Program (no. 2011D052;KYPT20121228160843692);Shenzhen Electronic Packaging Materials Engineering Laboratory (2012-372);Shenzhen basic research plan (JC201005270372A;JC201005270366A;JSGG20120615161915279);the National S&T Major Project (2011ZX02709-001)
语种英语
WOS记录号WOS:000329586300075
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/19266]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
4.Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
5.Chinese Univ Hong Kong, Dept Elect Engn, Hong Kong, Hong Kong, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Yu,Zhu, Pengli,Li, Gang,et al. Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink[J]. ACS Applied Materials and Interfaces,2014,6(1):560-567.
APA Zhang, Yu.,Zhu, Pengli.,Li, Gang.,Zhao, Tao.,Fu, Xianzhu.,...&Wong, Ching-ping.(2014).Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink.ACS Applied Materials and Interfaces,6(1),560-567.
MLA Zhang, Yu,et al."Facile Preparation of Monodisperse, Impurity-Free, and Antioxidation Copper Nanoparticles on a Large Scale for Application in Conductive Ink".ACS Applied Materials and Interfaces 6.1(2014):560-567.
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