Effect of lead on the sorption of 2,4,6-trichlorophenol on soil and peat
Pei, Zhi-guo; Shan, Xiao-quan; Liu, Tao; Xie, Ya-ning; Wen, Bei; Zhang, Shuzhen; Khan, Shahamat U.
2007
会议名称22nd IUFRO World Forestry Congress
会议日期AUG 08-13, 2005
会议地点Brisbane, AUSTRALIA
关键词sorption peat soil 2 lead 4 6-trichlorophenol
英文摘要The effect of lead on the sorption of 2,4,6-trichlorophenol (2,4,6-TCP) on soil and peat was investigated using a batch equilibration method. Lead markedly diminished the sorption of 2,4,6-TCP. and 2,4,6-TCP had little effect on lead sorption. Peat was a more effective adsorbent for 2,4,6-TCP than soil. The desorption hysteresis of 2,4,6-TCP verified the presence of high-energy sorption sites. Mechanisms of lead suppression effect on the 2,4,6-TCP sorption included the following: Firstly, lead accelerated the aggregation of colloids, the aggregates covered the surface in part and shrunk the pore sizes of the adsorbents, hence decreased the sorption of 2,4,6-TCP. Secondly, X-ray absorption and Fourier transform infrared spectroscopy study suggested that lead competed with 2,4,6-TCP for carboxylic, phenolic and Si-OH groups of organic matter and clay minerals. Such competition was partly responsible for the overall suppression effect of lead on the sorption of 2,4,6-TCP. (C) 2006 Elsevier Ltd. All rights reserved.
ISSN号0269-7491
内容类型会议论文
源URL[http://ir.rcees.ac.cn/handle/311016/24730]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式
GB/T 7714
Pei, Zhi-guo,Shan, Xiao-quan,Liu, Tao,et al. Effect of lead on the sorption of 2,4,6-trichlorophenol on soil and peat[C]. 见:22nd IUFRO World Forestry Congress. Brisbane, AUSTRALIA. AUG 08-13, 2005.
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