Graphene oxide decorated with silver nanoparticles as a coating on a stainless-steel fiber for solid-phase microextraction | |
Wang LC(王立成)1,2![]() ![]() ![]() ![]() | |
刊名 | Journal of Separation Science
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2015 | |
卷号 | 38期号:14页码:2439-2446 |
关键词 | Graphene oxide Polycyclic aromatic hydrocarbons Silver nanoparticles Solid-phase microextraction Stainless-steel wire |
ISSN号 | 1615-9306 |
通讯作者 | 郭勇 |
英文摘要 | A novel graphene oxide decorated with silver nanoparticles coating on a stainless-steel fiber for solid-phase microextraction was prepared. Scanning electron microscopy and X-ray photoelectron spectroscopy were used to characterize the coating surface and showed that silver nanoparticles were dispersed on the wrinkled graphene oxide surface. Coupled to gas chromatography with flame ionization detection, the extraction abilities of the fiber for polycyclic aromatic hydrocarbons were examined in the headspace solid-phase microextraction mode. The extraction parameters including adsorption time, adsorption temperature, salt concentration, desorption time and desorption temperature were investigated. Under the optimized condition, wide linearity with low limits of detection from 2 to 10 ng/L was obtained. The relative standard deviations for single-fiber repeatability and fiber-to-fiber reproducibility were less than 10.6 and 17.5%, respectively. The enrichment factors were from 1712.5 to 4503.7, showing the fiber has good extraction abilities. Moreover, the fiber exhibited a good stability and could be reused for more than 120 times. The established method was also applied for determination of polycyclic aromatic hydrocarbons in two real water samples and the recoveries of analytes ranged from 84.4-116.3% with relative standard deviations less than 16.2%. |
学科主题 | 分析化学与药物化学 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (21105107;21175143;21475143) |
语种 | 英语 |
WOS记录号 | WOS:000358001000009 |
公开日期 | 2015-12-24 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18510] ![]() |
专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 3.Univ Chinese Acad Sci, Chinese Acad Sci, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Wang LC,Hou XD,Li JB,et al. Graphene oxide decorated with silver nanoparticles as a coating on a stainless-steel fiber for solid-phase microextraction[J]. Journal of Separation Science,2015,38(14):2439-2446. |
APA | Wang LC,Hou XD,Li JB,Liu SJ,&Guo Y.(2015).Graphene oxide decorated with silver nanoparticles as a coating on a stainless-steel fiber for solid-phase microextraction.Journal of Separation Science,38(14),2439-2446. |
MLA | Wang LC,et al."Graphene oxide decorated with silver nanoparticles as a coating on a stainless-steel fiber for solid-phase microextraction".Journal of Separation Science 38.14(2015):2439-2446. |
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