Effect of grinding time on fabricating a stable methylene blue/palygorskite hybrid nanocomposite | |
Zhang Y(张媛)1,2; Wang WB(王文波)1![]() ![]() ![]() ![]() | |
刊名 | Powder Technology
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2015 | |
卷号 | 280页码:173-179 |
关键词 | Palygorskite Hybrid nanocomposites Grinding Microstructure Stability |
ISSN号 | 0032-5910 |
通讯作者 | 王爱勤 |
英文摘要 | The nanoscale dispersion of the crystal bundles or aggregates of natural palygorskite (PAL) is the key factor to prepare a stable PAL-based hybrid nanocomposite. The appropriate grinding process can effectively disaggregate the crystal bundles of PAL as dispersed nanorods and promote its interaction with organic molecules. In this study, a series of methylene blue/palygorskite (MB/PAL) hybrid nanocomposites were prepared by a facile mortar grinding process, and the effects of grinding time on their structure and stability were intensively investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FIR) spectra, Brunauer-Emmett-Teller (BET), thermal gravimetric analysis (TGA) and UV-vis techniques, as well as the resistance tests to acid, heat and UV-light. It was found that the control of grinding time is the key point affected the stability of hybrid structure, because it greatly influenced the removal of the water molecules, the change of d-spacing of (110) crystal plane and the organic/inorganic interaction between MB molecules and PAL. The aggregates of PAL crystals were highly dispersed as individual nanorods after being ground for 30 min, and the MB molecules are more easily to be adsorbed on the nanorods of PAL or be encapsulated in their channels, so the thermal stability, acid and UV-light resistance of the nanocomposites were evidently enhanced. |
学科主题 | 环境材料与生态化学 |
收录类别 | SCI |
资助信息 | the “863” Project of the Ministry of Science and Technology of the People's Republic of China (No. 2013AA032003);the Science and Technology Support Program of Jiangsu Province, Science and Technology Department (No. BE2014102) |
语种 | 英语 |
WOS记录号 | WOS:000356208700019 |
公开日期 | 2015-12-24 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18125] ![]() |
专题 | 兰州化学物理研究所_环境材料与生态化学研究发展中心 |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Xuyi Palygorskite Appl Technol, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Y,Wang WB,Mu B,et al. Effect of grinding time on fabricating a stable methylene blue/palygorskite hybrid nanocomposite[J]. Powder Technology,2015,280:173-179. |
APA | Zhang Y,Wang WB,Mu B,Wang Q,&Wang AQ.(2015).Effect of grinding time on fabricating a stable methylene blue/palygorskite hybrid nanocomposite.Powder Technology,280,173-179. |
MLA | Zhang Y,et al."Effect of grinding time on fabricating a stable methylene blue/palygorskite hybrid nanocomposite".Powder Technology 280(2015):173-179. |
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