Mussel-Inspired Thermosensitive Polydopamine-graft-Poly(N-isopropylacrylamide) Coating for Controlled-Release Fertilizer
Ma, Zhiyuan1; Jia, Xin1; Hu, Jiamei1; Liu, Zhiyong1; Wang, Heyun1; Zhou F(周峰)2
刊名Journal of Agricultural and Food Chemistry
2013
卷号61期号:50页码:12232-12237
关键词Thermoresponsive polydopamine PNIPAm ATRP controlled-release fertilizer
ISSN号0021-8561
英文摘要A thermoresponsive release multi-element compound fertilizer was first reported on the basis of a polydopamine-graft-poly(N-isopropylacrylamide) bilayer coated on a salty core by a combination of dopamine chemistry and surface-initiated atom transfer radical polymerization techniques, and the control of nutrient release in response to the environmental temperature was investigated. The successful synthesized stimuli-responsive fertilizers were confirmed by transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and gel permeation chromatography (GPC). The release of elements from fertilizer was determined by an inductively coupled plasma (ICP) emission spectrometer. The thermosensitive fertilizers exhibit outstanding stimuli-responsive permeability to encapsulated nutrients, and the release rate of coated elements can be tailored by the ambient temperature. They can release nutrients easily at T < lower critical solution temperature (LCST) but slow at T > LCST. This strategy of grafting thermoresponsive polymer brushes on polydopamine (Pdop)-coated substrates is useful to prepare a stimuli-responsive release system, which can adjust the release rate according to different conditions, and will be effective and promising in the research and development of a stimuli-sensitive controlled-release system.
学科主题材料科学与物理化学
收录类别SCI
资助信息the National Natural Science Foundation of China (21264013)
语种英语
WOS记录号WOS:000328865200007
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/18171]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Key Lab Chem Mat Xinjiang Uygur Autonomous Reg, Shihezi 832003, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Ma, Zhiyuan,Jia, Xin,Hu, Jiamei,et al. Mussel-Inspired Thermosensitive Polydopamine-graft-Poly(N-isopropylacrylamide) Coating for Controlled-Release Fertilizer[J]. Journal of Agricultural and Food Chemistry,2013,61(50):12232-12237.
APA Ma, Zhiyuan,Jia, Xin,Hu, Jiamei,Liu, Zhiyong,Wang, Heyun,&Zhou F.(2013).Mussel-Inspired Thermosensitive Polydopamine-graft-Poly(N-isopropylacrylamide) Coating for Controlled-Release Fertilizer.Journal of Agricultural and Food Chemistry,61(50),12232-12237.
MLA Ma, Zhiyuan,et al."Mussel-Inspired Thermosensitive Polydopamine-graft-Poly(N-isopropylacrylamide) Coating for Controlled-Release Fertilizer".Journal of Agricultural and Food Chemistry 61.50(2013):12232-12237.
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