Condition-Determined Multicomponent Reactions of 1,3-Dicarbonyl Compounds and Formaldehyde | |
Liu, Changhui1; Shen, Meng1; Lai, Bingbing1; Taheri, Amir1; Gu YL(顾彦龙)1,2 | |
刊名 | ACS Combinatorial Science |
2014 | |
卷号 | 16期号:11页码:652-660 |
关键词 | multicomponent reactions diversity-oriented synthesis condition-determined MCR combinatorial chemistry |
ISSN号 | 2156-8952 |
通讯作者 | 顾彦龙 |
英文摘要 | By means of changing the reaction parameters, different products could be generated selectively starting from the same combination of substrates involving 1,3-dicarbonyl compounds and formaldehyde. This strategy enabled us to access diverse molecules without changing both starting material and reactor, maximizing thus the multifunctionality of the synthetic system. For example, starting from a 1,3-dicarbonyl compound, formaldehyde and 1,1-diphenylethylene, two kinds of products could be selectively formed including (i) a densely substituted dihydropyran and (ii) a C2-cinnamyl substituted 1,3-dicarbonyl compound. A one-pot three-component reaction of phenacylpyridinium salt, 1,3-dicarbonyl compound, and formaldehyde was also investigated, which produced either 2,4-diacyl-2,3-dihydrofuran or 2,4-diacyl-2-hydroxylmethyl-2,3-dihydrofuran in good to excellent yield. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China (Grants 21173089;21373093);the Analytical and Testing Center of HUST. Chutian Scholar Program of the Hubei Provincial Government and the Cooperative Innovation Center of Hubei Province;the Fundamental Research Funds for the Central Universities of China (Grant 2014ZZGH019) |
语种 | 英语 |
WOS记录号 | WOS:000344721700009 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18794] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Large Format Battery Mat & Syst, Minist Educ, Wuhan 430074, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Changhui,Shen, Meng,Lai, Bingbing,et al. Condition-Determined Multicomponent Reactions of 1,3-Dicarbonyl Compounds and Formaldehyde[J]. ACS Combinatorial Science,2014,16(11):652-660. |
APA | Liu, Changhui,Shen, Meng,Lai, Bingbing,Taheri, Amir,&Gu YL.(2014).Condition-Determined Multicomponent Reactions of 1,3-Dicarbonyl Compounds and Formaldehyde.ACS Combinatorial Science,16(11),652-660. |
MLA | Liu, Changhui,et al."Condition-Determined Multicomponent Reactions of 1,3-Dicarbonyl Compounds and Formaldehyde".ACS Combinatorial Science 16.11(2014):652-660. |
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