Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation | |
Qin GP(秦贵平); Li LX(李立新); Li JW(李加文); Huang HM(黄汉民)![]() | |
刊名 | Journal of the American Chemical Society
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2015 | |
卷号 | 137期号:39页码:12490-12493 |
ISSN号 | 0002-7863 |
通讯作者 | 黄汉民 |
英文摘要 | A new strategy for selective insertion of metal carbenes into C–N bond has been developed via Pd-catalyzed C–N bond activation. A series of aminals and α-diazoesters with different substituents were successfully incorporated even in 0.1 mol % of catalyst under mild conditions, affording a wide range of α,β-diamino acid esters with quarternary carbon-centers. Preliminary mechanistic studies uncovered that the unique electrophilic cyclopalladated species could easily react with diazoacetates to generate a Pd-carbenoid intermediate which was involved in the catalytic cycle. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
语种 | 英语 |
WOS记录号 | WOS:000362628300018 |
公开日期 | 2015-12-24 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18645] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Qin GP,Li LX,Li JW,et al. Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation[J]. Journal of the American Chemical Society,2015,137(39):12490-12493. |
APA | Qin GP,Li LX,Li JW,&Huang HM.(2015).Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation.Journal of the American Chemical Society,137(39),12490-12493. |
MLA | Qin GP,et al."Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation".Journal of the American Chemical Society 137.39(2015):12490-12493. |
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