Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway

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	Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway
	Shen ZL(沈振陆)1; Chen, Meng 1; Fang, Tiantian 2; Li, Meichao 1; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Sun N(孙楠)1; Hu XQ(胡信全)1,3
刊名	Tetrahedron Letters
	2015
卷号	56 期号:21 页码:2768-2772
关键词	Functional group interconversion PMB ethers Carbonyl compounds Oxidation Oxygen
ISSN号	0040-4039
通讯作者	沈振陆 ; 胡信全
英文摘要	A facile and efficient protocol for direct transformation of p-methoxybenzyl (PMB) ethers to aldehydes or ketones via a catalytic aerobic oxidation process has been developed. The reaction was performed with the combination of catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,2,6,6-tetramethylpiperidine N-oxy (TEMPO), and tert-butyl nitrite (TBN), with molecular oxygen as terminal oxidant. A variety of PMB ether substrates derived from benzylic alcohols, heteroaromatic alcohols, and aliphatic alcohols, were converted to their corresponding carbonyl compounds in good conversions and selectivities.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21376224;21206147);Opening Foundation of Zhejiang Key Course of Chemical Engineering and Technology, Zhejiang University of Technology (20130211)
语种	英语
WOS记录号	WOS:000355036400030
公开日期	2015-12-24
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18444]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Shen ZL,Chen, Meng,Fang, Tiantian,et al. Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway[J]. Tetrahedron Letters,2015,56(21):2768-2772.
APA	Shen ZL.,Chen, Meng.,Fang, Tiantian.,Li, Meichao.,Mo WM.,...&Hu XQ.(2015).Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway.Tetrahedron Letters,56(21),2768-2772.
MLA	Shen ZL,et al."Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway".Tetrahedron Letters 56.21(2015):2768-2772.