Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines
	Zhang HY(张宏宇)1; Mao, Liu-Liang 1; Yang B(杨斌)1; Yang SD(杨尚东)1,2
刊名	Chemical Communications
	2015
卷号	51 期号:19 页码:4101-4104
ISSN号	1359-7345
通讯作者	杨尚东
英文摘要	A novel and convenient approach to the synthesis of various phosphorated indolines via a copper-catalyzed radical cascade cyclization reaction has been developed. The reaction employs cheap copper as the catalyst and K₂S₂O₈ as the oxidant under mild conditions. Various alkenes and P-radical precursors are compatible with this transformation. Preliminary mechanistic studies reveal that the addition of the P-radical may initiate the reaction, and then oxidative cyclization may be achieved to afford the desired product.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the NSFC (No. 21272100;21472076);FRFCU (lzujbky-2013-ct02);PCSIRT (IRT1138);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07)
语种	英语
WOS记录号	WOS:000350212600036
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18374]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhang HY,Mao, Liu-Liang,Yang B,et al. Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines[J]. Chemical Communications,2015,51(19):4101-4104.
APA	Zhang HY,Mao, Liu-Liang,Yang B,&Yang SD.(2015).Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines.Chemical Communications,51(19),4101-4104.
MLA	Zhang HY,et al."Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines".Chemical Communications 51.19(2015):4101-4104.