4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols

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	4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols
	Zhang SF(张淑芳); Miao CX(苗成霞); Xia CG(夏春谷); Sun W(孙伟)
刊名	ChemCatChem
	2015
卷号	7 期号:12 页码:1865-1870
关键词	acidity alcohols electron transfer oxidation
ISSN号	1867-3880
通讯作者	苗成霞 ; 孙伟
英文摘要	We have developed a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) derivative catalyzed oxidation of secondary alcohols with peracetic acid as the oxidant, which was generated from H2O2 and acetic acid catalyzed by strongly acidic resins. The oxidation of alcohols proceeded well through a shortened electron-transfer cycle under metal-free conditions, avoiding the use of any other electron-transfer mediators such as halides. In addition, we demonstrated that the present system exhibited excellent efficiency under mild conditions for the oxidation of aromatic, aliphatic, and allylic secondary alcohols.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (No. 21103207;21133011);the western light program of the Chinese Academy of Sciences (2012)
语种	英语
WOS记录号	WOS:000356311200014
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/18335]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhang SF,Miao CX,Xia CG,et al. 4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols[J]. ChemCatChem,2015,7(12):1865-1870.
APA	Zhang SF,Miao CX,Xia CG,&Sun W.(2015).4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols.ChemCatChem,7(12),1865-1870.
MLA	Zhang SF,et al."4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols".ChemCatChem 7.12(2015):1865-1870.