Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines | |
Zhang GY(张国营); Gao B(高宝); Huang HM(黄汉民) | |
刊名 | Angewandte Chemie International Edition |
2015 | |
卷号 | 54期号:26页码:7657-7661 |
关键词 | alkenes amines aminals palladium synthetic methods |
ISSN号 | 1433-7851 |
通讯作者 | 黄汉民 |
英文摘要 | A novel and efficient palladium-catalyzed hydroaminocarbonylation of alkenes with aminals has been developed under mild reaction conditions, and allows the synthesis of a wide range of N-alkyl linear amides in good yields with high regioselectivity. On the basis of this method, a cooperative catalytic system operating by the synergistic combination of palladium, paraformaldehyde, and acid was established for promoting the hydroaminocarbonylation of alkenes with both aromatic and aliphatic amines, which do not react well under conventional palladium-catalyzed hydroaminocarbonylation. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
语种 | 英语 |
WOS记录号 | WOS:000356390900037 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18329] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang GY,Gao B,Huang HM. Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines[J]. Angewandte Chemie International Edition,2015,54(26):7657-7661. |
APA | Zhang GY,Gao B,&Huang HM.(2015).Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines.Angewandte Chemie International Edition,54(26),7657-7661. |
MLA | Zhang GY,et al."Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines".Angewandte Chemie International Edition 54.26(2015):7657-7661. |
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