Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane | |
Wang H(王虎)1; Li L(李莉)1; Bai XF(柏惺峰)1; Shang, Jun-Yan1; Yang KF(杨科芳)1; Xu LW(徐利文)1,2 | |
刊名 | Advanced Synthesis and Catalysis
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2013 | |
卷号 | 355期号:2-3页码:341-347 |
关键词 | deoxygenation hydrogenolysis palladium reduction polymethylhydrosiloxane (PMHS) silanes |
ISSN号 | 1615-4150 |
通讯作者 | 杨科芳 ; 徐利文 |
英文摘要 | A simple method has been developed for the reductive deoxygenation of aromatic ketones and benzylic alcohols in the presence of polymethylhydrosiloxane (PMHS). The reductive deoxygenation of aromatic ketones and benzylic alcohols, including secondary alcohols, to the corresponding methylene hydrocarbons has been achieved in good to excellent yields using palladium chloride (PdCl2) as catalyst and PMHS as hydride source. Such deoxygenations were successfully with aryl alkyl ketones and diaryl ketones, as exemplified by the reductive deoxygenation of acetophenone and benzopheneone, respectively. The corresponding benzylic alcohols and secondary alcohol analogues could also be converted into their respective methylene hydrocarbons by the PdCl2/PMHS system. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (No. 21173064;51203037);Zhejiang Province Natural Science Foundation of China (Q12B020037);the Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT, JTAS 2011-01-014) |
语种 | 英语 |
WOS记录号 | WOS:000314653800015 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/18260] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Wang H,Li L,Bai XF,et al. Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane[J]. Advanced Synthesis and Catalysis,2013,355(2-3):341-347. |
APA | Wang H,Li L,Bai XF,Shang, Jun-Yan,Yang KF,&Xu LW.(2013).Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane.Advanced Synthesis and Catalysis,355(2-3),341-347. |
MLA | Wang H,et al."Efficient Palladium-Catalyzed CO Hydrogenolysis of Benzylic Alcohols and Aromatic Ketones with Polymethylhydrosiloxane".Advanced Synthesis and Catalysis 355.2-3(2013):341-347. |
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