Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 先进有机功能材料团队

	Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells
	Wen, Shuguang 1; Bao, Xichang 1; Shen, Wenfei 1,2; Gu, Chuantao 1; Du, Zhengkun 1; Han, Liangliang 1; Zhu, Dangqiang 1; Yang, Renqiang1
刊名	JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
	2014-02-15
卷号	52 期号:2 页码:208-215
关键词	bulk-heterojunction charge transfer conjugated polymer heteroatom-containing polymers organic solar cell poly(aryleneethynylene)s structure property relationships
英文摘要	The synthesis and characterization of building block of ethynylene-substituted benzo[1,2-b:4,5-b]dithiophene (BDT), and its application in the construction of poly(aryleneethynylene)s (PAEs) are described in this article. Alkoxy-substituted BDT and thiazolothiazole are selected as the other copolymerized units, and polymers of PEBBDT and PEBTTZ were synthesized by Pd-catalyzed Sonogashira coupling reaction. These polymers showed intense interchain - interaction and deep HOMO levels ( -5.50 eV). Bulk heterojunction solar cell fabricated using PEBBDT or PEBTTZ as electron donor and PC61BM as acceptor display power conversion efficiency of 0.85 and 2.40%, respectively, under the illumination of AM1.5G, 100 mW cm(-2). This study shows good prospect for the application of PAEs-type polymers in organic solar cell. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 208-215
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Polymer Science
研究领域[WOS]	Polymer Science
关键词[WOS]	OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PROPERTIES ; SIDE-CHAINS ; POLYMER ; DONOR ; MORPHOLOGY ; EFFICIENCY ; COPOLYMER ; DESIGN
收录类别	SCI
语种	英语
WOS记录号	WOS:000328051600007
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/6381]
专题	青岛生物能源与过程研究所_先进有机功能材料团队
作者单位	1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Qingdao Univ, Inst Hybrid Mat, Lab New Fiber Mat & Modern Text, Growing Base State Key Lab, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Wen, Shuguang,Bao, Xichang,Shen, Wenfei,et al. Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2014,52(2):208-215.
APA	Wen, Shuguang.,Bao, Xichang.,Shen, Wenfei.,Gu, Chuantao.,Du, Zhengkun.,...&Yang, Renqiang.(2014).Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,52(2),208-215.
MLA	Wen, Shuguang,et al."Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 52.2(2014):208-215.