Synthesis of Novel Polydiazocine for Electroactive Materials Based on Diazocine | |
Li, Jianzhong1; Wan, Xiaobo2 | |
刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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2013-11-01 | |
卷号 | 51期号:21页码:4694-4701 |
关键词 | heteroatom-containing polymers nonlinear polymers oligomers polycondensation synthesis |
英文摘要 | In this study, we successfully designed and synthesized a novel class of ladder-type polymer polydi-benzoyl[b,f][1,5]diazocine (PBDA-a) and polydimethoxybenzoyl[b,f][1,5]diazocines (PBDA-b) for novel electrochemical actuators via one-pot polymerization. The structure of polymers was characterized using C-13 NMR, FTIR and MALDI-TOF. Both of the polydiazocines exhibited high thermal stability and excellent solubility in common solvent. Molecular conformation studies using the density functional theory method revealed that the conformational structure of PBDA-a preferred to display zigzag conformation while PBDA-b display helix conformation. The mechanism of the polydiazocine synthesis is assumed to condensation polymerization proceeding by an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by the dimerization to form diazocine ring. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4694-4701 |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Polymer Science |
研究领域[WOS] | Polymer Science |
关键词[WOS] | ELECTROMECHANICAL ACTUATORS ; PERFORMANCE ; POLYPYRROLE ; DEVICES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000325090000025 |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/6044] ![]() |
专题 | 青岛生物能源与过程研究所_生物基及仿生高分子材料团队 |
作者单位 | 1.Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Qingdao 266109, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioproc Technol, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jianzhong,Wan, Xiaobo. Synthesis of Novel Polydiazocine for Electroactive Materials Based on Diazocine[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2013,51(21):4694-4701. |
APA | Li, Jianzhong,&Wan, Xiaobo.(2013).Synthesis of Novel Polydiazocine for Electroactive Materials Based on Diazocine.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,51(21),4694-4701. |
MLA | Li, Jianzhong,et al."Synthesis of Novel Polydiazocine for Electroactive Materials Based on Diazocine".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 51.21(2013):4694-4701. |
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