An rht type metal-organic framework based on small cubicuboctahedron supermolecular building blocks and its gas adsorption properties

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 多相催化转化团队

	An rht type metal-organic framework based on small cubicuboctahedron supermolecular building blocks and its gas adsorption properties
	Li, Liangjun 1,2; Tang, Sifu 1; Lv, Xiaoxia 1,2; Jiang, Min 1; Wang, Chao 1,2; Zhao, Xuebo 1
刊名	NEW JOURNAL OF CHEMISTRY
	2013
卷号	37 期号:11 页码:3662-3670
英文摘要	A metal-organic framework NPC-5 was synthesized via reaction of a methyl-functionalized ligand 2,4,6-trimethyl benzene-1,3,5-triyl-isophthalate (TMBTI) with Co(NO3)(2)center dot 6(H2O) under solvothermal conditions. The steric hindrance induced by the methyl groups on the central phenyl ring led to a non-planar configuration of the ligand and further resulted in a small cubicuboctahedron SBB sustained (3, 24)-connected rht network, which comprised three types of cages and exhibited high porosity. Experimental results showed that despite the use of different synthetic methods the same structure was obtained. Gas sorption study of this MOF revealed high CO2 and CH4 uptake capacities and relatively low adsorption enthalpies.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	NANOSCALE FACETED POLYHEDRA ; HIGH H-2 ADSORPTION ; CARBON-DIOXIDE ; METHANE STORAGE ; RETICULAR SYNTHESIS ; ACTIVATED CARBONS ; ROOM-TEMPERATURE ; SINGLE-CRYSTAL ; SURFACE-AREAS ; ZEOLITE 13X
收录类别	SCI
语种	英语
WOS记录号	WOS:000325763700040
公开日期	2015-12-24
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/5992]
专题	青岛生物能源与过程研究所_多相催化转化团队
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Jinan 266101, Shandong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Liangjun,Tang, Sifu,Lv, Xiaoxia,et al. An rht type metal-organic framework based on small cubicuboctahedron supermolecular building blocks and its gas adsorption properties[J]. NEW JOURNAL OF CHEMISTRY,2013,37(11):3662-3670.
APA	Li, Liangjun,Tang, Sifu,Lv, Xiaoxia,Jiang, Min,Wang, Chao,&Zhao, Xuebo.(2013).An rht type metal-organic framework based on small cubicuboctahedron supermolecular building blocks and its gas adsorption properties.NEW JOURNAL OF CHEMISTRY,37(11),3662-3670.
MLA	Li, Liangjun,et al."An rht type metal-organic framework based on small cubicuboctahedron supermolecular building blocks and its gas adsorption properties".NEW JOURNAL OF CHEMISTRY 37.11(2013):3662-3670.